• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
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    • 专利摘要:
    Composition for a film or thermoplastic layer and its uses. The present invention relates to an ultraviolet light (uv) photosensitive filter composition as an essential element in a film or thermoplastic layer to act as an adjustable filter for stabilization of light exposure. Said film or thermoplastic layer with the present filter composition can gradually block the uv light and is almost transparent to visible light. The uv light-sensitive filter composition comprises effective amounts of metal oxide nanoparticles selected from titanium oxide, cerium oxide, and zinc oxide. Said nanoparticles are treated with inorganic and organic coatings and, dispersed inside a substrate at a certain concentration, they can act as an adjustable uv light filter, particularly for agricultural greenhouse films or packaging films, where it is desired to protect from the uv light to everything under the substrate. (Machine-translation by Google Translate, not legally binding)
    公开号:ES2574752A1
    申请号:ES201630163
    申请日:2016-02-11
    公开日:2016-06-21
    发明作者:Grégory Michel COUÉ；Juan Ignacio DUCH TUESTA
    申请人:Plasticos Compuestos S A；Plasticos Compuestos Sa；
    IPC主号:
    专利说明:

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    UHMW), medium density (MDPE), low density (LDPE), linear low density (LLDPE, VLDPE, ULDPE). As "polypropylene" we define a thermoplastic that is obtained by the polymerization of propylene or propene. The term "polypropylene" comprises homopolymers or copolymers. Polypropylene homopolymers (PPH) fall into three categories (isotactic PPH, atactic PPH or syndiotactic PPH), while polypropylene copolymers (PPC) are divided into random copolymer or block copolymer. As "polystyrene" we define a thermoplastic polymer that is obtained from the polymerization of monomeric styrene. Of the different types of polystyrene (PS), crystal polystyrene or GPPS (General Purpose Polystyrene) has the property of being transparent, rigid and brittle. As "polycarbonates" we define a group of thermoplastics that are easy to work, mold and thermoforming and that have a number of interesting advantages such as their high transparency, dimensional stability, high weather resistance and high resistance to impact and stiffness.
    The polymers or substrates used in the present invention are preferably transparent to visible light. In the present patent, optically transparent means that at least 80%, preferably at least 85%, and more preferably at least 90% of the light in the range of the visible can pass through it. In general, the absorption or transmission capacity of UV and visible radiation is determined by UV-VIS spectroscopy.
    A thermoplastic polymer is defined as a plastic that, at relatively high temperatures, becomes deformable or flexible, melts when heated and hardens when it cools sufficiently, which can be used in various applications such as films, containers, insulators, ceramics, pipes, toys, packaging and / or garbage bags, and not limited to any known in the art.
    In another aspect of the invention, the UV light photosensitive composition may comprise a mineral (b) known in the art, but preferably selected from a titanium oxide, cerium oxide, and / or zinc oxide.
    The process of transforming UV radiation into heat energy is different when compared to an organic UV light absorber. The nano-sized titanium dioxide particles act as a photosemiconductor and can absorb UV radiation. During this process an electron is promoted from the Valencia band to the conduction band.
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    In addition, the dispersibility and compatibility between the nanoparticles and the matrix containing them can be improved. This second coating must be based on a hydrophobic organic material. With this second coating of the nano-sized titanium dioxide particles, its dispersion and its distribution in the organic matrix are homogenized.
    In a further aspect of the invention the composition comprises a second coating of the metal oxide nanoparticles (b) wherein said organic coating Do is an organosiloxane.
    In addition, the filter composition of the present invention essentially comprises an organic UV stabilization substance (c) selected from a sterically hindered amine. In general, the term "sterically hindered amine" is known in the art. Sterically hindered amines are a class of organic UV light stabilizers and often referred to as "HALS" (light stabilizers based on sterically hindered amine, or in English Hindered Amines Light Stabilizers).
    Examples for sterically hindered amines may be the following, but not limited to these: Bis (2,2,6,6-tetramethyl-4-piperidyl) sebacate, bis (2,2,6,6-tetramethyl-4-piperidyl ) succinate, bis (1,2,2,6,6-pentamethyl-4-piperidyl) sebacate, bis (1-octyloxy-2,2,6,6-tetramethyl-4piperidyl) sebacate, bis (1,2,2 , 6,6-pentamethyl-4-piperidyl) n-butyl-3,5-di-tert-butyl-4-hydroxybenzylmalonate, the condensation of 1- (2-hydroxyethyl) -2,2,6,6-tetramethyl-4-hydroxypiperidine and succinic acid, linear or cyclic condensations of N, N'-bis (2,2,6,6-tetramethyl-4-piperidyl) hexamethylenediamine and 4-tert-octylamino-2,6-dichloro-1,3,5-triazine, tris (2,2,6,6-tetramethyl-4-piperidyl) nitrilotriacetate, tetrakis (2,2,6,6-tetramethyl-4-piperidyl-1,2,3,4butantetracarboxylate, 1,1 '- (1,2 -ethanediyl) -bis (3,3,5,5-tetramethylpiperazinone), 4-benzoyl2,2,6,6-tetramethylpiperidine, 4-stearyloxy-2,2,6,6-tetramethylpiperidine, bis (1,2,2 , 6,6pentamethylpiperidyl) -2-n-butyl-2- (2-hydroxy-3,5-di-tert-butylbenzyl) -malonate, 3-n-octyl-7 , 7,9,9 tetramethyl-1,3,8-triazaspiro [4.5] decane-2,4-dione, bis (1-octyloxy-2,2,6,6-tetramethylpiperidyl) sebacate, bis (1-octyloxy-2,2 , 6,6-tetramethylpiperidyl) succinate, cyclic or linear condensations of N, N'-bis (2,2,6,6-tetramethyl-4piperidyl) hexamethylenediamine and 4-morpholino-2,6-dichloro-1,3,5 -triazine, the condensation of 2-chloro-4,6-bis (4-n-butylamino-2,2,6,6-tetramethylpiperidyl) -1,3,5-triazine and 1,2-bis (3aminopropylamino) -ethane, the condensation of 2-chloro-4,6-di- (4-n-butylamino-1,2,2,6,6pentamethylpiperidyl) -1,3,5-triazine and 1,2-bis (3-aminopropylamino) ethane , 8-acetyl-3-dodecyl
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    corrugated sheets, films, mono-oriented films, biaxially oriented films, lamination films and finishing films. This film can be used in products for the agricultural industry such as greenhouses, small tunnels, films for plant protection, films to cover silage
    5 of fertilizer, pressed paper and woven and non-woven meshes.
    Preferred polymers are low density polyethylene (LDPE), linear low density polyethylene (LLDPE), high density polyethylene (HDPE), ethylene vinyl acetate copolymers (EVA), polypropylene (PP), polystyrene (PS), copolymer styrene acrylonitrile (SAN), polylactic acid (PLA), polyamide (PA), polyethylene terephthalate (PET) and / or polycarbonate (PC). Filter films usually comprise a monolayer or a coextruded layer. The thickness of the filter films can be variable and usually ranges from 10 to 200 µm. Thermoplastic films for wrapping packaging or for agricultural applications are representative of the various thermoplastic films to which the
    Composition-UV-sensitive filter of the present invention.
    These types of materials, such as those described in this patent, can also be used in cotton, wool, silk, polyester, polyamide, polyamide / elastane and other fabrics, and also in packaging products such as bottles and bottles, where the content is
    20 sensitive to UV radiation.
    Example 1 Masterbatch manufacturing (MB1)
    A certain amount of nanometric titanium dioxide (b) with both Di and Do coatings, a polymer process aid and an LDPE (Alcudia 2202F) with a flow rate of 0.25 g / 10 min (190 ° C / 2, 16 kg) are processed in the form of granules, which were previously mixed using a mechanical stirrer.
    30 This mixture is placed in a dispenser and the extrusion of this mixture and the subsequent granulation was carried out in a double screw extruder, which allowed a good mixing of the components. The extrusion temperature did not exceed 200 ° C in the head area. In order to avoid thermal degradation of the product, the temperature was maintained
    35 below 200 ° C as in other areas of the extruder, where the temperature was set below 180 ° C. 14
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    The obtained masterbatch (MB1) contained 20% by weight of titanium dioxide nanoparticles (b) coated by both inorganic and organic coatings Di and Do.
    Example 2 Manufacture of Films 1 and 2
    A mixture comprised of 5% masterbatch (MB1), 7.5% of a masterbatch containing 20% by weight of HALS additive of high molecular weight 1,3,5-triazine-2,4,6-triamine, N , N '"[- diyl-bis 1,2-ethane [[[4,6-bis- [butyl (1,2,2,6,6-pentamethyl-4-piperidinyl) amino] -1,3,5 -triazine-2-yl] imino] -3,1-propanediyl]] bis [N ', N "-dibutyl-N', N '-bis (1,2,2,6,6-pentamethyl-4-piperidinyl) methylated and LDPE (Alcudia 2202F) which has a flow rate of 0.25 g / 10 min (190 ° C / 2.16 kg) in the form of granules became a single layer film with a total thickness of 150 µm using an extruder of Collin blown film, E30Px25 L / D. This film was designated as "Film 1" and contains 1% of nanoparticles of titanium dioxide (b) coated by both inorganic and organic coatings Di and Do.
    A mixture comprised of 2.5% masterbatch (MB1), 7.5% of a masterbatch containing 20% by weight of HALS additive of high molecular weight 1,3,5-triazine-2,4,6-triamine , N, N '"- [- diyl-bis 1,2-ethane [[[4,6-bis- [butyl (1,2,2,6,6-pentamethyl-4-piperidinyl) amino] -1, 3,5-triazine-2-yl] imino] -3,1-propanediyl]] bis [N ', N "-dibutyl-N', N '-bis (1,2,2,6,6-pentamethyl-4-piperidinyl) methylated and LDPE (Alcudia 2202F) which has a flow rate of 0.25 g / 10 min (190 ° C / 2.16 kg) in the form of granules became a single layer film with a total thickness of 150 µm using a blown film extruder Collin, E30Px25 L / D. This film was designated as "Film 2" and contains 0.5% titanium dioxide nanoparticles (b) coated by both Di and Do inorganic and organic coatings.
    Example 3 Film Manufacturing 3
    A mixture consisting of 7.5% of a masterbatch containing 20% by weight of HALS additive of high molecular weight 1,3,5-triazine-2,4,6-triamine, N, N '"- [- diyl-bis 1,2-ethane [[[4,6-bis- [butyl (1,2,2,6,6-pentamethyl-4-piperidinyl) amino] -1,3,5-triazine-2-yl ] imino] -3,1-propanediyl]] bis [N ', N "-dibutyl-N', N '-bis (1,2,2,6,6-pentamethyl-4-piperidinyl) methylated and LDPE (Alcudia 2202F) with a flow rate of 0.25 g / 10 min (190 ° C / 2.16 kg) in the form of granules, it was transformed into a 150 µm thick film using a
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    权利要求:
    Claims (1)
    [1]
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    同族专利:
    公开号 | 公开日
    ES2574752B1|2017-03-14|
    引用文献:
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    WO2008113075A1|2007-03-15|2008-09-18|Nanovere Technologies, Inc.|Dendritic polyurethane coating|
    US20100120965A1|2007-03-28|2010-05-13|Masako Kikuchi|Optical Organic-Inorganic Composite Material and Optical Element|
    WO2009153231A2|2008-06-20|2009-12-23|Basf Se|Agrochemical formulation comprising a pesticide, an organic uv photoprotective filter and coated metal oxide nanoparticles|
    EP2868717A1|2013-11-01|2015-05-06|Shin-Etsu Chemical Co., Ltd.|Titania-containing coating composition and coated article|CN109220420A|2018-08-08|2019-01-18|云南曲靖塑料有限公司|A kind of high-intensitive three layers of double-colored agricultural mulching and preparation method thereof|
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